Magic Lith Prototype Update #3

No pictures this time because the results have been pretty boring. Basically, I’ve found that a magic lith formulation can be a lot more flexible than expected, with the primary requirement being a relatively high amount of hydroquinone and a relatively high pH. I’ve done some tests with alkaline prebaths. This seems to help the evenness of a print significantly, but comes with it’s own problems. The print can’t be rinsed after the prebath or else it returns to hardened form and will develop unevely. If the prebath is too alkaline and/or soaked for too long, the print will have a mottle-like effect, but will develop evenly otherwise and quite quickly with the low contrast image appearing rather quickly and then infectious development occurring throughout the print. If done properly the print can also be pulled more quickly and thus with more color. Thus far my best results have been with 2.5m with 1.5L of water + 15ml of 3% hydroxide.

I’ve changed to using a larger tray and 2L of developer at a time which seems to help the evenness as well as tray life but is not a complete solution.

Benzotriazole is an essential component in this developer. Without it, you will get both peppering and yellow staining on the border. With ~5ml/L both will go away. Too much seems to make the uneven development problem worse though.

Bromide is not as terrible as expected. I don’t really understand, but it has more effect in a carbonate based developer than a hydroxide developer, even if both are around the same pH. Iodide is optional.. I can’t really see a huge effect when it is present with bromide, even with a large amount of iodide. With very small or no bromide it does work as a restrainer of sorts, but not a good one.

HQ amount is still a bit of a mystery. More HQ will produce better blacks, but also cause more overall development. High amounts of HQ will produce some fogging with long development times and thus if higher contrast is desired, then going close to the normal print time (rather than massive over exposing) will produce a low contrast image which will then be affected by infectious development to produce proper blacks and darkening of low mid tones.

Ortho Litho/PFS Experiment Report Nov 15, 2019

No fancy pictures because all I used was a step chart and enlarger.. but did test and find out a number of things.

  • PFS-4 mixed with photographic grade TEA (ie, clear not yellow) is not as potent. Seems to require double the working strength and 25% more time for equivalent results. It does seem somewhat more stable to use with photographic TEA with less fogging, but actually looks to lose ~1/2 stop in unstable speed compared to technical grade TEA. Timing and such could potentially be adjusted further with pH balancing

  • PFS-4 as a stock solution seems to keep pretty much forever. The batch I mixed in August is still just as good today

  • PFS-4 can not be replaced by a simple carbonate+bromide solution. It’s clearly the TEA itself that is doing something to the film, not just having a basic environment with bromide present

  • The “stable” speed increase of Arista Ortho Litho with PFS-4 is ~2 stops. The unstable (ie, can be fogged/show artifacts) speed increase is ~3 stops.

  • PFS-4 is effective on Kodalith, though to a much lesser extent. The speed of Kodalith with nothing special is about 2.5 stops faster than Arista, and PFS-4 only adds 0.5-1 stop extra, though does seem to degrade the highlights somewhat and thus resulting in a more pleasant tonal scale, rather than going very dark on the negative, they go to a more mild grey. End result is that the speed of Kodalith with PFS-4 roughly matches that of Arista, but with a steeper contrast curve.

  • PFS-4 does NOT work on Kodak positive microfilm (ie, what FPP sells). Absolutely no difference is made between the two. Also, a fun fact people don’t mention is that it is blue sensitive only and can be processed under red safelight, maybe even amber safelight